E. Solutions and Solubility · Solutions and SolubilitySafe Drinking Water: Treatment, Standards and Choices
E1.2 E2.8 E2.2 A1.9 A1.10 A2.1About 75 minutes
Learning goals- I can describe the main steps of municipal water treatment and the chemistry of coagulation and disinfection.
- I can compare test results for drinking water with Canadian guidelines and draw conclusions.
- I can analyse economic, social and environmental issues related to drinking water, including bottled water, the Walkerton tragedy and drinking water advisories in First Nations communities.
- I can name careers in water quality and the training they need.
Words to know
potable water
Water that is safe to drink.
maximum acceptable concentration (MAC)
The highest concentration of a substance allowed in drinking water under Health Canada's guidelines.
coagulation
Adding a chemical (such as alum) whose positive ions neutralize the charges on tiny suspended particles so they clump together.
floc
A loose clump of particles and precipitate that forms during flocculation and settles out.
disinfection
Killing or inactivating disease-causing microorganisms, e.g. with chlorine, ultraviolet light or ozone.
chlorine residual
The small amount of chlorine left in treated water to keep it safe as it travels through the pipes.
drinking water advisory
A public notice telling people not to drink the water, or to boil it first, because it may be unsafe.
What comes out of the tap
In most Ontario towns, you can fill a glass at the kitchen tap and drink it without a second thought. Behind that glass is a treatment plant, a network of pipes, a lab that tests water every day, licensed operators, and laws. In this final lesson you will put your solution chemistry to work: you will see the chemistry of treatment, compare test results with Canadian standards, and analyse the economic, social and environmental issues around drinking water.
Remember from this unit
You can now express tiny concentrations in mg/L (ppm) and µg/L (ppb), explain precipitation and pH, and you know how pollutants enter water (the water pollution lesson). Every one of those skills is used in a drinking-water lab.
How a municipal plant treats water
- Intake and screening: water from a lake, river or wells passes through screens that remove fish, weeds and debris.
- Coagulation and flocculation: a coagulant such as alum (aluminium sulfate) is added. Tiny clay and organic particles in raw water carry negative charges and repel each other, so they never settle. The positive Al³⁺ ions neutralize those charges, and in the slightly basic water they also form a sticky aluminium hydroxide precipitate, Al(OH)₃(s). Slow mixing grows these into fluffy clumps called flocs, which trap particles and many microbes.
- Sedimentation: the flocs settle to the bottom as sludge.
- Filtration: water passes through layers of sand, gravel and often activated carbon, which also removes some taste and odour compounds.
- Disinfection: chlorine (or chloramine), ultraviolet light or ozone kills or inactivates bacteria, viruses and parasites. Chlorine is added so that a small chlorine residual stays in the water all the way to your tap.
- Other adjustments: the pH may be raised slightly so the water does not dissolve lead or copper from old pipes, and some municipalities add fluoride to help prevent tooth decay.
Rural homes with private wells are responsible for their own testing; many public health units offer free bacteria testing kits for well water.
The main steps in a typical municipal water treatment plant. Real plants differ; some use membrane filters or extra steps.Coagulation: negatively charged particles repel and stay suspended. Positive aluminium ions neutralize their charges, so they clump into flocs that can settle out. Not to scale.Standards: how clean is clean enough?
Health Canada publishes the Guidelines for Canadian Drinking Water Quality, which set maximum acceptable concentrations (MACs) based on health research. Ontario's Safe Drinking Water Act, 2002 and its regulations make standards like these legal requirements for municipal systems, require regular testing in licensed labs, and require operators to be certified. Many municipalities post an annual drinking-water report online.
There are also aesthetic objectives for things that affect taste, smell or colour but are not a health risk at normal levels, such as chloride (about 250 mg/L or less) and iron.
| Substance | Canadian guideline (MAC) | Why it matters |
|---|
| E. coli | none detectable in 100 mL | sign of fecal contamination; can cause serious illness |
| lead | 0.005 mg/L (5 µg/L) | harms the developing brain; comes mostly from old pipes and solder |
| arsenic | 0.010 mg/L (Health Canada has proposed lowering it to 0.005 mg/L) | natural in some bedrock; long-term cancer risk |
| nitrate (as N) | 10 mg/L (45 mg/L as nitrate) | from fertilizer and manure; dangerous for infants |
| fluoride | 1.5 mg/L (0.7 mg/L recommended where added) | too much causes tooth and bone effects |
Selected maximum acceptable concentrations (MACs) from Health Canada's Guidelines for Canadian Drinking Water Quality. Ontario's legal standards for municipal systems follow these guidelines.Worked exampleExample 1: Does the water meet the standard?
A private well test reports: lead 3.0 µg/L, nitrate (as N) 12 mg/L, E. coli 0 per 100 mL, arsenic 0.004 mg/L. Compare each with the table and make a recommendation.
- Lead: 3.0 µg/L = 0.0030 mg/L < 0.005 mg/L → meets the guideline.
- Nitrate (as N): 12 mg/L > 10 mg/L → exceeds the guideline by 20%.
- E. coli: none detected → meets.
- Arsenic: 0.004 mg/L < 0.010 mg/L → meets.
- Conclusion: the water is not acceptable because of nitrate. Infants especially should not drink it or have formula made with it. Boiling does not remove nitrate (it concentrates it). Recommend a treatment system (such as reverse osmosis), a different water source, and checking for nearby fertilizer or manure sources.
Only nitrate fails (12 mg/L vs 10 mg/L as N). Do not use for infants; treat or replace the source; boiling does not help.
Walkerton, 2000: why the rules exist
In May 2000, the drinking water of Walkerton, Ontario became contaminated with E. coli O157:H7 and other bacteria after heavy rain washed manure from a nearby farm into a shallow town well. Chlorination and testing at the well were not done properly. Seven people died and more than 2300 became ill. A public inquiry led by Justice Dennis O'Connor recommended major changes, which led to the Safe Drinking Water Act, 2002, mandatory operator training and certification, licensed testing labs, and the Clean Water Act, 2006, which protects the sources of drinking water (lakes, rivers and aquifers) from contamination. This is the "source to tap" approach: protect the source, treat the water, and test it.
Drinking water in First Nations communities
Many First Nations communities in Canada have lived under long-term drinking water advisories, some for many years. Causes include water systems that were too small or poorly funded, difficulties keeping certified operators, and remote locations. Drinking water on reserves is a shared federal responsibility with First Nations. Since November 2015, more than 150 long-term advisories have been lifted (158 by September 2026, when 38 were still in effect in 36 communities) through new plants, upgrades and operator training, much of it led by the communities themselves, but some advisories remain in effect, including in Ontario. Safe water is also tied to culture: many First Nations, Métis and Inuit people describe water as a living relative to be protected, and Indigenous water protectors lead work to safeguard lakes and rivers for future generations.
Bottled water: economic, social and environmental issues
- Cost: in most Ontario municipalities tap water costs well under one cent per litre, while bottled water usually costs 100 times as much or more.
- Environment: making, transporting and disposing of plastic bottles uses energy and creates waste; not all bottles are recycled. Groundwater taking permits for bottling plants have caused public debate in Ontario.
- Health and regulation: bottled water is regulated as a food under federal law, while municipal tap water is tested under provincial rules. Both are safe in most of Canada. Bottled water can be essential during an advisory or emergency.
- Global equity: in many low-income countries, unsafe water and poor sanitation still cause hundreds of thousands of deaths each year, mostly from diarrhoeal diseases among young children. Affordable solutions include protected wells, household chlorination and filtration.
Emerging issue: pharmaceuticals and microplastics
Trace amounts of medicines and personal-care products (often measured in nanograms per litre) pass through wastewater plants and appear in rivers. Treatment plants were not designed to remove them, and scientists are still studying the long-term effects. Studies have also found microplastic particles in both tap and bottled water. These are active areas of research for environmental chemists.
Worked exampleExample 2: Cost comparison
A family drinks 6 L of water per day. Tap water costs $3.50 per 1000 L (including wastewater charges). Bottled water costs $0.75 per litre in a case. Find the yearly cost of each.
- Water per year = 6 L × 365 = 2190 L.
- Tap: 2190 L × ($3.50 ÷ 1000 L) = $7.67 per year.
- Bottled: 2190 L × $0.75/L = $1642.50 per year.
- Ratio: 1642.50 ÷ 7.67 ≈ 214 times more expensive.
Tap: about $8 per year. Bottled: about $1640 per year.
Careers in water quality (A2.1)
- Water treatment or wastewater operator: runs plants and tests water; in Ontario, operators must be certified (college programs in water quality or environmental technology are common).
- Environmental or analytical chemist: measures pollutants in labs (university degree in chemistry).
- Laboratory technician/technologist: runs daily tests (college diploma).
- Public health inspector: investigates outbreaks and advises well owners (degree plus certification).
- Civil or environmental engineer: designs treatment plants and pipe networks (engineering degree and licence).
Just for funWater treatment operators sometimes call the fluffy aluminium hydroxide clumps "floc." So yes, an important part of their job is to watch the floc go by.
Hands-on activityTest your own tap water and read your water report
You need: drinking-water or pool/aquarium test strips for pH, total hardness and free chlorine (available at hardware or pet stores), a clean glass, and a computer or phone.
- Run the cold tap for 30 seconds, then fill the glass.
- Dip each strip as the package directs and compare the colours with the chart. Record pH, hardness and free chlorine.
- Find your municipality's annual drinking-water report online (search your town's name + "drinking water annual report"). Find the values it reports for the same properties, plus lead and nitrate.
- Make a table: property, your result, the report's result, the Canadian guideline or operational range (pH about 7.0 to 10.5 is the usual operating range for treated water).
- Write a conclusion: does your water meet the guidelines? How reliable are test strips compared with a licensed lab (A1.9)?
What to look for: treated tap water usually has a pH between 7 and 8.5 and a small chlorine residual (often below about 2 mg/L). Hardness varies widely across Ontario (it is not a health issue). If you are on a private well, ask a grown-up about the free well-water bacteria test from your local public health unit. Do not drink pool test chemicals; throw used strips in the garbage.
Your turn
1List the main steps of municipal water treatment in order.
Screening → coagulation/flocculation → sedimentation → filtration → disinfection → storage/distribution (with a chlorine residual).
2Explain how alum helps remove tiny suspended particles.
Positive Al³⁺ ions neutralize the negative charges on particles so they stop repelling, and aluminium hydroxide precipitate forms sticky flocs that trap particles and settle.
3Why is a chlorine residual kept in the water?
To keep killing microbes that might enter the water in the pipes on its way to homes.
4A test shows lead at 8 µg/L. Does it meet the MAC? What is a likely source?
No: 8 µg/L > 5 µg/L (0.005 mg/L). Likely source: old lead service pipes or lead solder in the home's plumbing.
5What happened in Walkerton in 2000, and name one law that followed.
E. coli contaminated the town water after manure washed into a well, and treatment and testing failed; seven people died and over 2300 became ill. The Safe Drinking Water Act, 2002 (or the Clean Water Act, 2006) followed.
6Give one economic and one environmental argument against routinely buying bottled water when tap water is safe.
Economic: it costs 100 or more times as much as tap water. Environmental: plastic waste and energy for manufacturing and transport.
7Name two careers in drinking-water quality and the training for each.
Sample: water treatment operator (college program + Ontario certification); analytical chemist (university chemistry degree); lab technician (college diploma); public health inspector (degree + certification).
More practice: warm-up
Maximum acceptable concentration.
2What is the MAC for E. coli in drinking water?
None detectable in 100 mL.
3Name two methods of disinfection.
Any two: chlorine, chloramine, UV light, ozone.
4Who publishes the Guidelines for Canadian Drinking Water Quality?
Water that is safe to drink.
More practice: on your own
1Why doesn't boiling make water with high nitrate safe?
Boiling kills microbes but does not remove dissolved nitrate; as water evaporates, the nitrate becomes more concentrated.
2A town is choosing between upgrading its treatment plant ($20 million) and protecting the land around its well field from manure and fuel spills. Explain why the Walkerton inquiry would recommend doing both.
The inquiry promoted a multi-barrier, source-to-tap approach: protecting the source reduces contamination entering the plant, and treatment plus testing catches what still gets through. Each barrier covers failures in the others.
3Explain two reasons why some First Nations communities have faced long-term drinking water advisories.
Any two: water systems that were underfunded or too small, difficulty training and keeping certified operators, remote locations that make parts and expertise hard to get, and poor source water.
4Calculate: a lab finds 0.75 µg of arsenic in a 50.0 mL sample. Does it meet the MAC of 0.010 mg/L?
c = 0.75 µg ÷ 0.0500 L = 15 µg/L = 0.015 mg/L, which is above 0.010 mg/L: it does not meet the MAC.
5Evaluate this claim: 'Bottled water is always purer than tap water.' (A1.9)
Not supported. In most Canadian municipalities tap water meets strict, frequently tested standards; some bottled water is treated municipal water. Both can be safe; bottled water is mainly important where tap water is unsafe or during emergencies. Reliable evidence would be test results from licensed labs, not advertising.
Challenge
1Write the equation for the formation of the aluminium hydroxide floc when alum dissolves in slightly basic water, and the net ionic equation.
Al₂(SO₄)₃(aq) + 6 OH⁻ (from the water's natural alkalinity or added lime) → 2 Al(OH)₃(s) + 3 SO₄²⁻(aq). Net ionic: Al³⁺(aq) + 3 OH⁻(aq) → Al(OH)₃(s).
2A treatment plant serves 50 000 people who each use 250 L of water per day. The plant keeps a chlorine dose of 1.5 mg/L. What mass of chlorine is used per day, in kilograms?
Volume = 50 000 × 250 L = 1.25 × 10⁷ L. Mass = 1.5 mg/L × 1.25 × 10⁷ L = 1.875 × 10⁷ mg = about 19 kg per day.
3Propose a plan, with at least three actions, to make sure a small remote community has safe drinking water over the long term. Justify each action using ideas from this unit.
Sample plan: (1) Protect the source (keep sewage and fuel away from the intake), reducing pollutants before treatment. (2) Build a plant with coagulation, filtration and disinfection sized for the community, with backup power. (3) Train and fund local certified operators from the community, so expertise stays there. (4) Regular testing in a licensed lab for E. coli, lead and other contaminants, compared with Canadian MACs, with results shared publicly. (5) Plan with the community, respecting its knowledge of and relationship with the water.
Check your understandingQuiz
1. Which treatment step uses alum to clump tiny particles?
2. Why is a chlorine residual left in treated water?
3. The MAC for lead in Canadian drinking water is 0.005 mg/L. A sample has 2 µg/L. It
4. The Walkerton tragedy (2000) was caused mainly by
5. Which law protects the sources of drinking water in Ontario?
6. Boiling water that has a high nitrate concentration
7. Which career requires provincial certification to run a water treatment plant in Ontario?
For parents and teachersBig idea (E1.2, E2.8): safe drinking water depends on chemistry (coagulation, disinfection, testing against standards) and on decisions about money, law, fairness and the environment.
How to help: Do the test-strip activity together and look up your town's annual water report. Talk about whether your family buys bottled water and why. If you have a private well, this is a good time to arrange a bacteria test through your public health unit.
Sensitive topics: the Walkerton tragedy involved deaths, and some First Nations communities continue to experience drinking water advisories. Talk about these respectfully, focusing on causes and solutions; present First Nations communities as leaders of their own solutions, not only as people affected.
Common difficulties: converting µg/L and mg/L when comparing with a MAC; thinking boiling fixes every problem (it kills microbes but does not remove chemicals like nitrate or lead).
Safety: test strips are safe but not for drinking; throw them away after use.