Grade by Grade
E. Solutions and Solubility · Solutions and Solubility

Water Pollution: Sources and Cumulative Effects

E1.1 E2.2 A1.9 A1.10About 70 minutes
Learning goals
  • I can name major sources of water pollutants, including landfill leachate, agricultural runoff, industrial effluent, municipal wastewater and road salt.
  • I can explain eutrophication, bioaccumulation and biomagnification and why pollutant effects add up over time and space.
  • I can use concentration data (ppm, ppb, mg/L) to judge whether a pollutant is a concern.
  • I can describe how mercury pollution has affected First Nations communities in northwestern Ontario, and evaluate solutions.

Words to know

point source
A pollutant source that comes from one identifiable place, such as a factory outflow pipe.
non-point source
Pollution spread over a wide area, such as runoff from many farm fields, lawns or roads.
leachate
Liquid formed when water trickles through waste (e.g. in a landfill) and dissolves or carries away substances from it.
effluent
Liquid waste discharged into a river, lake or sea, for example from a factory or sewage plant.
eutrophication
Over-enrichment of a water body with nutrients (mainly phosphorus and nitrogen), causing algal blooms and oxygen loss.
bioaccumulation
The build-up of a substance in an organism's tissues over its lifetime, because it is taken in faster than it is removed.
biomagnification
The increase in concentration of a substance at each higher level of a food chain.
cumulative effects
The combined effect of many sources, or of a pollutant building up over time.

Everything ends up downstream

In spring, snowmelt runs off a farmer's field, a shopping mall parking lot and a highway, and it all flows into the same creek. Each source alone might add only a small amount of fertilizer, salt or oil. Together, over years, the amounts add up. This lesson is about where water pollutants come from, why their effects are cumulative, and how chemists use the concentration skills you just learned to measure them.

Remember from Grade 9 and this unit

In Grade 9 you studied ecosystems and how human activity affects them. In this unit you have learned that water dissolves many substances (it is polar) and how to express tiny concentrations in ppm and ppb.

Major sources of water pollutants

Agricultural runoff (non-point): rain and snowmelt wash fertilizers (nitrates and phosphates), manure (nutrients and bacteria) and pesticides off fields into ditches and streams. Golf courses and lawns can add fertilizer runoff in the same way, especially when they are heavily fertilized and irrigated.

Landfill leachate (point): rain trickling through garbage dissolves substances such as ammonia, metals and organic compounds. Modern Ontario landfills have liners and collection pipes to capture leachate and send it for treatment, but older dumps may not.

Industrial effluent (point): factories, mines, pulp and paper mills and food processors (such as poultry or meat plants) discharge wastewater. Depending on the industry, it may carry metals, acids, nutrients, warm water or organic matter that uses up oxygen as it decays.

Municipal wastewater (point): sewage treatment plants remove most solids, bacteria and nutrients, but traces of medicines, personal-care products and microplastics can pass through.

Road salt (non-point): in Canadian winters, sodium chloride (and some calcium chloride) is spread on roads. The chloride dissolves, does not break down, and can build up in streams, lakes and groundwater.

river / lakefarm fieldrunoff: N, P, manurelandfillleachateindustryeffluentroad: salt, oilsewage plantnon-point sources: spread out
Several sources can feed the same water body. Pipes and sites (industry, sewage plant, landfill) are point sources; runoff from fields and roads is non-point. Not to scale.

Cumulative effect 1: eutrophication

Phosphorus is usually the nutrient that limits algae growth in fresh water. When extra phosphorus (and nitrogen) arrives from fertilizer, manure or sewage, algae grow explosively. When they die, bacteria decompose them and use up dissolved oxygen. Fish and other animals can suffocate, and some blooms (blue-green algae, also called cyanobacteria) make toxins.

Lake Erie, the shallowest and warmest Great Lake, has repeated large algal blooms in its western basin, linked mainly to phosphorus from farm runoff. Canada and the United States have agreed on targets to reduce the phosphorus entering the lake.

extra N and Penter lakealgae growfast (bloom)algae die andsinkdecomposersuse up O₂low O₂:fish dieEutrophication: too many nutrients lead to too little oxygen
Eutrophication is a chain of events. Notice that the harm (low oxygen) comes several steps after the cause (extra nutrients).

Cumulative effect 2: bioaccumulation and biomagnification

Some pollutants, such as methylmercury (a form of mercury made by bacteria in water and sediment) and some pesticides, are absorbed by living things but removed very slowly. They bioaccumulate: an older fish has more than a young one. Each predator eats many prey, so the concentration rises at each level of the food chain: biomagnification. Large predatory fish such as walleye and northern pike can carry far higher mercury concentrations than the water around them. That is why Ontario publishes a Guide to Eating Ontario Fish with advice by lake, species and size.

water: 0.000 01 ppmplankton: 0.01 ppmsmall fish: 0.1 ppmwalleye: 1 ppmIllustrative values: each step up the food chain concentrates mercury about 10 times or more.
Biomagnification of mercury (example values, for illustration only). The water may contain very little mercury, yet top predators can carry concentrations many thousands of times higher.

Mercury in the English-Wabigoon River system

In the 1960s, a chemical plant connected to the pulp and paper mill in Dryden, Ontario, discharged mercury into the Wabigoon River, which flows into the English River system. The mercury built up in fish. Downstream, the Anishinaabe communities of Grassy Narrows First Nation (Asubpeeschoseewagong Netum Anishinabek) and Wabaseemoong Independent Nations depend on the river for fishing, food, jobs as fishing guides, and cultural practices. Many community members have experienced health effects linked to mercury, and the contamination has affected their economy and way of life.

The mercury is still in the river sediments today. Community members and leaders continue to lead the push for cleanup of the river, for health care and for compensation, and governments have committed funding for remediation and health supports. This case shows cumulative effects clearly: a pollutant released decades ago, at low concentrations in water, still affects people through the food chain.

When you research cases like this, use reliable sources (A1.9): community statements, government reports and peer-reviewed studies, and notice whose voices each source includes.

Worked example

Example 1: Is the pollutant a concern?

A stream below a landfill has 0.015 mg/L of lead. Upstream it has 0.001 mg/L. A guideline for protecting aquatic life in soft water is about 0.001 mg/L to 0.007 mg/L, depending on water hardness (use 0.004 mg/L here). (a) Convert both values to ppb. (b) How many times higher is the downstream value than the upstream value? (c) Is the downstream value a concern?

  1. (a) 1 mg/L ≈ 1 ppm = 1000 ppb. Downstream: 0.015 mg/L = 15 ppb. Upstream: 0.001 mg/L = 1 ppb.
  2. (b) 15 ÷ 1 = 15 times higher downstream. The landfill is a likely source (leachate).
  3. (c) 15 ppb is above the 4 ppb guideline used here, so yes, it is a concern and should be investigated (test more samples, check the landfill's leachate system).

15 ppb downstream vs 1 ppb upstream: 15 times higher and above the guideline.

Worked example

Example 2: Adding up road salt

A small lake receives road-salt runoff each winter. Its chloride concentration was 20 mg/L in 1990 and 110 mg/L in 2025. (a) What was the average increase per year? (b) A Canadian long-term guideline for chloride to protect aquatic life is 120 mg/L. If the trend continues, about when will the lake reach it? (c) Why is this called a cumulative effect?

  1. (a) Increase = 110 − 20 = 90 mg/L over 35 years = about 2.6 mg/L per year.
  2. (b) 120 − 110 = 10 mg/L to go; 10 ÷ 2.6 ≈ 4 years, so around 2029.
  3. (c) Each winter's salt adds a little chloride, and chloride does not break down or settle out, so it builds up year after year.

About 2.6 mg/L per year; it could reach 120 mg/L around 2029; the effect builds up over many winters.

Just for fun

In 1992, a shipping container spilled thousands of plastic bath toys (including yellow ducks) into the Pacific Ocean. Oceanographers tracked where they washed up for years and used them to learn about ocean currents: the same currents that carry real pollutants around the world.

Hands-on activity

Storm drain detective (and a nutrient jar test)

Part A: storm drains. With a grown-up, walk around your block. Count the storm drains (the grates at the curb). In most Ontario towns, storm drains carry rainwater and snowmelt to a creek or lake without treatment. For each drain, list what could wash into it: road salt, oil drips, soap from car washing, pet waste, lawn fertilizer, litter. Rank the three most likely pollutants on your street. Stay on the sidewalk and away from traffic.

Part B: nutrient jars (2 weeks). You need two clean glass jars, tap water left out overnight, a spoonful of pond or puddle water (collected by a grown-up), and a houseplant fertilizer. Fill both jars with the same water and add the same spoonful of pond water to each. To one jar only, add a tiny amount of fertilizer (a grown-up measures it; read the label and wash hands after). Put both jars on a sunny windowsill, label them, and photograph them every few days.

What to look for: the jar with fertilizer usually turns greener and cloudier as algae grow faster. That is a small model of eutrophication. Name the independent variable (fertilizer), the dependent variable (algae growth) and two controlled variables. Pour the water outside on soil when done, not into a storm drain.

Your turn

1

Is a factory outflow pipe a point or non-point source?

2

Name two pollutants in farm runoff.

3

What is leachate and where does it come from?

4

Explain the difference between bioaccumulation and biomagnification.

5

Why does adding phosphorus to a lake eventually lower its dissolved oxygen?

6

A river sample has 0.0004 mg/L of mercury. Express this in ppb.

7

Why does chloride from road salt build up in lakes over many years?

More practice: warm-up

1

Give one example of a non-point source.

2

Which nutrient usually limits algae growth in fresh water?

3

What do modern landfills use to stop leachate escaping?

4

Name one large predatory fish that can carry high mercury levels.

5

What is effluent?

More practice: on your own

1

A golf course near a stream fertilizes heavily and waters every evening. Explain how this could harm the stream, and suggest two changes.

2

Wastewater from a poultry farm is high in nutrients and organic matter. Predict two effects on a small creek.

3

Water has 0.000 02 ppm of a pesticide; a fish has 2.0 ppm. By what factor is the pesticide concentrated in the fish?

4

Explain why the mercury released in the 1960s can still affect people downstream today.

5

A student uses a single social-media post as evidence that a lake is polluted. Suggest better sources.

Challenge

1

A city wants to reduce phosphorus reaching a lake. Compare two solutions: (a) adding a precipitation step at the sewage plant, (b) paying farmers to plant buffer strips. Which sources does each address?

2

Explain why a pollutant that is below a guideline in a river can still be a problem for people who eat fish from that river.

3

A lake's chloride rose from 15 mg/L to 60 mg/L over 30 years. Assume a steady rise. Predict its value after another 10 years and name two ways a town could slow the increase.

Check your understanding

Quiz

1.

Which is a point source?

2.

Leachate is

3.

Eutrophication is mainly caused by excess

4.

Biomagnification means a pollutant's concentration

5.

0.0020 mg/L of lead equals about

6.

Why do chloride levels in many Ontario lakes keep rising?

For parents and teachers

Big idea (E1.1): many sources, each small, can add up; some pollutants also concentrate in food chains, so effects are cumulative over time and distance.

How to help: Do the storm-drain walk together and talk about what goes down the drain at your home. Discuss news stories about algae blooms or fish advisories; ask your teen to identify the source and whether it is point or non-point.

Sensitive topic: this lesson discusses mercury pollution affecting Grassy Narrows First Nation and Wabaseemoong Independent Nations. These are living communities that continue to lead efforts for cleanup and health care. Encourage your teen to seek out the communities' own statements when researching, and to avoid describing people only as victims.

Common difficulties: confusing bioaccumulation (one organism, over time) with biomagnification (up a food chain); mixing up ppm and ppb.

Safety: a grown-up should collect pond water and handle fertilizer; wash hands afterwards. Stay on the sidewalk during the storm-drain walk.